Oxidative cyclization of acrylonitrile complexed to cobalt, and a subsequent phosphine-exchange reaction, gives the trans-(4) and two cis-isomers (5) and (6) of η5-cyclopentadienyl(dimethylphenylphosphine)dicyanocobaltacyclopentane; the isomerization mechanism has been examined kinetically.
Y. Wakatsuki and H. Yamazaki, J. Chem. Soc., Chem. Commun., 1980, 1270 DOI: 10.1039/C39800001270
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