The complex [RuCl(CO)(bipy)2]Cl, a product of the long term reaction of RuCl3.3H2O with 2 mol of bipyridyl (bipy) in refluxing dimethylformamide, produces H2, CO, and CO2 on photolysis in water; under CO the photochemical water–gas shift reaction is catalytic.
D. J. Cole-Hamilton, J. Chem. Soc., Chem. Commun., 1980, 1213 DOI: 10.1039/C39800001213
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