From a comparison of the reactions of alkynols (1a) and (1b) with lithium aluminium deuteride, a specific solvent role in alkynol reductions is identified and is in keeping with the observed marked solvent-dependence of product ratios.
J. W. Blunt, M. P. Hartshorn, M. H. G. Munro, L. T. Soong, R. S. Thompson and J. Vaughan, J. Chem. Soc., Chem. Commun., 1980, 820 DOI: 10.1039/C39800000820
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