A manganese(II) penta-co-ordinated complex with monodentate urea ligands; X-ray crystal structure of dibromotris-(NN′-dimethylurea)manganese(II)
Abstract
X-Ray structure analysis shows that the high-spin complex dibromotris(NN′-dimethylurea-O)manganese(II) has a trigonal bipyramidal geometry with the bromine atoms in equatorial positions and with two types of bonding for the neutral ligands, one of them being very unusual.