Quenching of the title cation (3) with lithium methoxide results in stereo- and regio-specific incorporation of the methoxy group to give (4); the high specificity of the quench reaction is controlled by orbital symmetry.
R. H. A. M. Brounts, P. Schipper and H. M. Buck, J. Chem. Soc., Chem. Commun., 1980, 522 DOI: 10.1039/C39800000522
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