Issue 11, 1980

Control over the dimerisation of cyclo-octatetraene through metal complexation: X-ray structure of [Mo(CO)4(C16H16)]

Abstract

Cyclo-octatetraene reacts with [Mo(CO)6] in boiling octane to produce [Mo(CO)4(C16H16)], shown by X-ray diffraction to contain a new dimer of the hydrocarbon arising formally from a combination of [2 + 2]π and [2 + 4]π cycloaddition; the dimer is released as a stable species upon treatment of the complex with Me3NO.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 518-520

Control over the dimerisation of cyclo-octatetraene through metal complexation: X-ray structure of [Mo(CO)4(C16H16)]

A. H. Connop, F. G. Kennedy, S. A. R. Knox, R. M. Mills, G. H. Riding and P. Woodward, J. Chem. Soc., Chem. Commun., 1980, 518 DOI: 10.1039/C39800000518

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements