Issue 7, 1980

Base-catalysed decomposition of nitramide: Brønsted relations and a second reaction pathway

Abstract

A new spectroscopic technique for measuring the rate of nitramide decomposition revealed a second pathway for this reaction and allowed extension of the Brønsted relation for the first (traditional) pathway into more basic regions where the onset of relatively sharp curvature was detected; these results suggest a mechanism for the first reaction pathway in which proton transfer is not concerted with heavy atom reorganization.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 309-310

Base-catalysed decomposition of nitramide: Brønsted relations and a second reaction pathway

A. J. Kresge and Y. C. Tang, J. Chem. Soc., Chem. Commun., 1980, 309 DOI: 10.1039/C39800000309

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