Determination of the crystal and molecular structure of the hydrochloride of phenyl-(t-butyl)-phosphinic amide, [Ph(But)P(O)NH2]2·HCl, shows that the acidic proton is located between the two phosphoryl oxygen atoms, clearly demonstrating preferred O-protonation of the amide function.
W. Wong-Ng, S. C. Nyburg and T. A. Modro, J. Chem. Soc., Chem. Commun., 1980, 195 DOI: 10.1039/C39800000195
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