The complexes [Rh2(C5Me5)2(OH)3]+(1), [M2(C5Me5)2Cl4], M = Rh or Ir, [Ru2(p-cymene)2Cl4], and [Ru2(C6Me6)2(OH)3]+ all catalyse the disproportionation of acetaldehyde to acetic acid and ethanol in water in the absence of base, and other aldehydes react similarly; rhodium hydride complexes can be isolated from the reactions involving (1).
J. Cook, J. E. Hamlin, A. Nutton and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1980, 144 DOI: 10.1039/C39800000144
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