The heterogeneous reaction of adamantane with sulphur dioxide on supported metal and oxide catalysts gave mainly adamantanone with yields of up to 38%. The reaction of butanes on supported metal catalysts gave 5-methyl-2,3-dithiacyclopent-4-enethione. Both systems were studied in the temperature range 300–450°C.
N. Samman, J. Chem. Soc., Perkin Trans. 2, 1979, 529 DOI: 10.1039/P29790000529
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