A stereospecific synthesis of pseudoclovene-B (1), a rearranged sesquiterpene artifact, is reported. 1-Methyltricyclo[6.3.1.03,8]dodeca-3,6-dien-5-one (6), an advanced intermediate in this synthesis and a skeletal representative of many other natural products, has been prepared by two different routes utilising Winstein's Ar1–6 solvolytic cyclisation as the key step.
S. Chatterjee, A. Sarkar and P. C. Dutta, J. Chem. Soc., Perkin Trans. 1, 1979, 2914 DOI: 10.1039/P19790002914
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