The flash thermolysis of 1,2-oxathiolan 2-oxides (1) has been shown to lead to a mixture of cyclopropanes and alkenes. When a stabilising group is present at the 5-position as in (1a) and (1b) only cyclopropanes are obtained.
T. Durst, J. D. Finlay and D. J. H. Smith, J. Chem. Soc., Perkin Trans. 1, 1979, 950 DOI: 10.1039/P19790000950
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