Issue 24, 1979

Carbon monoxide transfer to a metal co-ordinated carbyne ligand: X-ray crystal structure of [Mn2{µ-C(CO)C6H4-Me-p}(CO)6(η-C5H5)]·0·5Et2O

Abstract

The mononuclear cationic carbyne complexes [M[triple bond, length half m-dash]C·C6H4Me-p-(CO)2(η-C5H5)]BF4(M = Mn or Re) react with [(Ph3P)2N][Mn(CO)5] to give compounds [MMn{µ-C(CO)·C6H4Me-p}(CO)6(η-C5H5)]·0·5Et2O in which a CO ligand has transferred to the bridging group; the structure of the dimanganese compound has been established by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 1168-1169

Carbon monoxide transfer to a metal co-ordinated carbyne ligand: X-ray crystal structure of [Mn2{µ-C(CO)C6H4-Me-p}(CO)6(η-C5H5)]·0·5Et2O

J. Martin-Gil, J. A. K. Howard, R. Navarro and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1979, 1168 DOI: 10.1039/C39790001168

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