An X-ray crystal structure determination shows that, as a consequence of helices of hydrogen bonds, crystalline exo-2,exo-6-dihydroxy-2,6-dimethylbicyclo[3.3.1]nonane comprises a network of separate helical canals, lined only with hydrocarbon hydrogen atoms, which trap a variety of guest molecules.
R. Bishop and I. Dance, J. Chem. Soc., Chem. Commun., 1979, 992 DOI: 10.1039/C39790000992
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