Interaction of hexamethyltungsten(VI) with trimethylphosphine; X-ray crystal structure of dimethyltetrakistrimethylphosphinetungsten(II)
Abstract
The synthesis of WMe6·PMe3, trans-WMe2(PMe3)4, WH2(PMe3)5, NbMe5(PMe3)2, and TaMe5(PMe3)2 is reported; the structure of trans-WMe2(PMe3)4 has been determined by a single crystal X-ray analysis.