Issue 20, 1979

A neutral thiolate–cycloheptatrienone adduct: the first direct evidence of base addition at two different, unsubstituted cycloheptatrienone carbon atoms

Abstract

2-(Dimethylthio)tropone tetrafluoroborate gives a ca. 1:1 equilibrium mixture of two neutral adducts after methanethiolate attack at C(3) and C(7), which slowly change into the adduct of methanethiolate attack on 2(methylthio)tropone.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 912-913

A neutral thiolate–cycloheptatrienone adduct: the first direct evidence of base addition at two different, unsubstituted cycloheptatrienone carbon atoms

M. Cavazza, G. Morganti, C. A. Veracini and F. Pietra, J. Chem. Soc., Chem. Commun., 1979, 912 DOI: 10.1039/C39790000912

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