SCHEDULED MAINTENANCE:
Treatment of the 1H-1,2-benzodiazepines (1) with lead tetra-acetate affords the previously unknown 5H-1,2-benzodiazepines (2), which, on treatment with base, undergo tautomerization to the 1H-isomers (5), and on photolysis give the indole (8).
T. Tsuchiya and J. Kurita, J. Chem. Soc., Chem. Commun., 1979, 803 DOI: 10.1039/C39790000803
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