MgII and MnII 2-oxoimidazolidine-1-carboxylato-complexes, [graphic omitted]CO2M(OMe), which were isolated from the reaction of the metal dimethoxides, imidazolidin-2-one, and CO2 act as CO2 carriers in transferring the CO2 unit to cyclohexanone; the ureido structure of the complexes plays an importantant role in this transfer.
T. Tsuda, Y. Chujo, T. Hayasaki and T. Saegusa, J. Chem. Soc., Chem. Commun., 1979, 797 DOI: 10.1039/C39790000797
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