Bifunctional azido-compounds such as benzohydroximic azide, α-azidobenzaldehyde 2,4-dibromophenylhydrazone, trans-1-azido-2-hydroxycyclohexane, 2-azido-1-phenylethanol, 2-azidobenzyl alcohol, o-azidoaniline, and α-azidoacetophenones react with a variety of phosphorus(III) reagents to give pentaco-ordinate amino-(oxy)- and diamino(oxy)-phosphoranes.
J. I. G. Cadogan, I. Gosney, E. Henry, T. Naisby, B. Nay, N. J. Stewart and N. J. Tweddle, J. Chem. Soc., Chem. Commun., 1979, 189 DOI: 10.1039/C39790000189
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