From the first order rate constants for the decomposition of ten substituted dibenzylmercury compounds at 140·2 °C, a scale of substituent constants σ· has been derived, which measures the stabilizing effect of substituents at the para position of a benzyl free radical.
S. Dinçtürk, R. A. Jackson and M. Townson, J. Chem. Soc., Chem. Commun., 1979, 172 DOI: 10.1039/C39790000172
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