π-Excessive heterocycles and arenes activated by one or more strongly electron donating substituents undergo a copper catalysed reaction with 2,5-dichlorothiophenium bismethoxycarbonylmethylide to give moderate to excellent yields of aryl malonates.
R. J. Gillespie and A. E. A. Porter, J. Chem. Soc., Chem. Commun., 1979, 50 DOI: 10.1039/C39790000050
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