Gallicin, a new germacranolide, was isolated from Artemisia maritima gallica Willd and assigned structure (3a) on chemical and spectroscopic evidence. Its absolute configuration was determined by the fact that it can be converted to the dihydrosantamarin (5) by a biogenetic cyclization process.
A. G. González, J. Bermejo, H. Mansilla, A. Galindo, J. M. Amaro and G. M. Massanet, J. Chem. Soc., Perkin Trans. 1, 1978, 1243 DOI: 10.1039/P19780001243
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