The equilibrium constant for protium–deuterium exchange between methanol and water at 25 °C has been calculated from new measurements, employing vapour-phase exchange over supported platinum catalysts, of the deuterium separation factor between molecular hydrogen and liquid methanol.
D. E. Clegg and J. H. Rolston, J. Chem. Soc., Chem. Commun., 1978, 1037 DOI: 10.1039/C39780001037
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