The ionization ratio [NO2+]/[HNO3] of nitric acid, in 80–96% sulphuric acid, has been evaluated by Raman and u.v. methods; the thermodynamic pKa of the equilibrium involved has been calculated by using the Mc activity coefficient function.
N. C. Marziano, P. G. Traverso, A. De Santis and M. Sampoli, J. Chem. Soc., Chem. Commun., 1978, 873 DOI: 10.1039/C39780000873
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