Issue 9, 1978

Thermodynamics of formation of 18-crown-6 complexes with arenediazonium and anilinium salts in methanol at 25 °C

Abstract

Binding of 18-crown-6 to arenediazonium cations, which has previously been shown to stabilize the cation against decomposition, is found to be very sensitive to electronic factors and much more sensitive to steric factors than is binding to corresponding anilinium cations.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 386-387

Thermodynamics of formation of 18-crown-6 complexes with arenediazonium and anilinium salts in methanol at 25 °C

R. M. Izatt, J. D. Lamb, B. E. Rossiter, N. E. Izatt, J. J. Christensen and B. L. Haymore, J. Chem. Soc., Chem. Commun., 1978, 386 DOI: 10.1039/C39780000386

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