The formation of N-methylthiomethylketenimines from the reaction of α-cyanoalkyl-dimethylsulphonium salts with n-butyl-lithium or triethylamine occurs by way of a [2,3] sigmatropic rearrangement of intermediate ylides.
G. Morel, S. Khamsitthideth and A. Foucaud, J. Chem. Soc., Chem. Commun., 1978, 274 DOI: 10.1039/C39780000274
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