An unusually stable thionitrite from N -acetyl- D , L -penicillamine; X -ray crystal and molecular structure of 2-(acetylamino)-2-carboxy-1,1-dimethylethyl thionitrite

Lamar Field; Robert V. Dilts; Ramanathan Ravichandran; P. Galen Lenhert; Gary E. Carnahan

doi:10.1039/C39780000249

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DOI: 10.1039/C39780000249 (Paper) J. Chem. Soc., Chem. Commun., 1978, 249-250

An unusually stable thionitrite from N-acetyl-D,L-penicillamine; X-ray crystal and molecular structure of 2-(acetylamino)-2-carboxy-1,1-dimethylethyl thionitrite

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Lamar Field, Robert V. Dilts, Ramanathan Ravichandran, P. Galen Lenhert and Gary E. Carnahan

Abstract

N-Acetyl-D,L-penicillamine (1) was converted by HNO₂ into a thionitrite (3) which was stable as a solid and atypically so even in solution; X-ray structural parameters are given for (3), and both homolytic and heterolytic reactions are described.