The comparison of kinetic parameters for ligand exchange with those for the octahedral to square-planar structural interconversion of a complex of nickel(II) provides direct evidence for a five-co-ordinate transition state for the ligand exchange process.
J. Sachinidis and M. W. Grant, J. Chem. Soc., Chem. Commun., 1978, 157 DOI: 10.1039/C39780000157
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