SCHEDULED MAINTENANCE:
In the formation of the 4α–6α-η-PdCl complex from 2,2-dimethylcholest-4-en-3-one initial π-complexing appears to be rate-limiting, and in the proton elimination step, k 6β2H/k 6α1H =ca. 1.
K. Henderson and F. J. McQuillin, J. Chem. Soc., Chem. Commun., 1978, 15 DOI: 10.1039/C39780000015
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