SCHEDULED MAINTENANCE:
A semiempirical calculation on fluoromethane in water has been perfomed to establish the number and kind of different ion pairs, whose existence has been suggested as intermediates in solvolytic reactions. The calculations predict the existence of three species: their geometric and electronic structures are discussed.
P. Cremaschi, A. Gamba and M. Simonetta, J. Chem. Soc., Perkin Trans. 2, 1977, 162 DOI: 10.1039/P29770000162
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