The aminoglycoside 66-40 C, produced as a minor component in the fermentation of Micromonospora inyoensis, has been shown by spectroscopic and chemical degradative studies to have the novel dimeric structure (5), containing αβ-unsaturated imine groups not previously encountered in any aminoglycoside antibiotic.
D. H. Davies, A. K. Mallams, J. McGlotten, J. B. Morton and R. W. Tkach, J. Chem. Soc., Perkin Trans. 1, 1977, 1407 DOI: 10.1039/P19770001407
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