The moderating efficiency of HF for energetic tritium atoms, αHF, is evaluated from the results of quasi-classical trajectory calculations for non-reactive encounters. αHF is shown to vary with energy, particularly in the energy region where the reaction cross section is large. The implications of this variation on kinetic analyses of hot atom experiments are considered.
D. J. Malcolme-Lawes, J. Chem. Soc., Faraday Trans. 2, 1977, 73, 1222 DOI: 10.1039/F29777301222
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