The generalized integral adsorption isotherm and main thermodynamic functions for localized monolayer adsorption of gas mixtures on heterogeneous solid surfaces have been derived on the basis of statistical thermodynamics. Two-component adsorption systems have been discussed in detail.
M. Jaroniec, J. Chem. Soc., Faraday Trans. 2, 1977, 73, 933 DOI: 10.1039/F29777300933
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