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H-n.m.r. spectroscopy has been used to demonstrate that nucleophilic attack by pyridine on the C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
C bond in cis-dichloro(π-ethene)(pyridine)platinum(II) readily leads to the formation of the σ-bonded complex, cis-dichloro(pyridine)(2-pyridinioethanide)platinum(II), which is much more stable than the corresponding trans isomer.
I. M. Al-Najjar and M. Green, J. Chem. Soc., Chem. Commun., 1977, 926 DOI: 10.1039/C39770000926
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