The configurational equilibria of diastereoisomeric 2-isopropyl-5-iodo-1,3-dioxans heavily favour the equatorial iodides at room temperature in all solvents studied: ΔG0, –1·92 (C6H12), –1·35 (C6H6), –1·43 (CHCl3), and –0·95 kcal mol–1(MeCN).
N. J. Kotite, M. Harris and M. K. Kaloustian, J. Chem. Soc., Chem. Commun., 1977, 911 DOI: 10.1039/C39770000911
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