The isomerization of butenes on TiO2 proceeds through three different mechanisms, involving, respectively, protonic sites, Lewis acid sites, and basic sites, depending on the pretreatment temperature of the TiO2 catalyst.
J. Lemberton, G. Perot and M. Guisnet, J. Chem. Soc., Chem. Commun., 1977, 883 DOI: 10.1039/C39770000883
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