Issue 16, 1977

Catalysis by chlorohydridobis(triphenylphosphine)ruthenium(II) species. Novel kinetics and their implications for activation of saturated hydrocarbons

Abstract

Novel kinetics for hydrogenation of acrylamide catalysed by [{HRuCl(PPh3)2}2] in solution indicate a mechanism which includes competitive oxidative addition reactions of H2 and propionamide (C–H cleavage) to ruthenium(I) centres.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 550-551

Catalysis by chlorohydridobis(triphenylphosphine)ruthenium(II) species. Novel kinetics and their implications for activation of saturated hydrocarbons

B. R. James and D. K. W. Wang, J. Chem. Soc., Chem. Commun., 1977, 550 DOI: 10.1039/C39770000550

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