The molecular ions of MeCHS and CH2![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CHSH interconvert, possibly via a ring opened ethylene sulphidetype intermediate; it is however only the MeCHS radical cation which fragments by hydrogen atom loss in the microsecond time-scale.
J. L. Holmes, P. Wolkoff and J. K. Terlouw, J. Chem. Soc., Chem. Commun., 1977, 492 DOI: 10.1039/C39770000492
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