The alkaloid naucléfine has been synthesised from 1,2,3,4-tetrahydro-1-methylene-2-nicotinoyl-β-carboline by the action of benzyl bromide, followed by debenzylation; the problem of isomer formation is avoided and the overall yield is 55%.
M. Sainsbury and N. L. Uttley, J. Chem. Soc., Chem. Commun., 1977, 319 DOI: 10.1039/C39770000319
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