Forward (k1) and backward (k–1) rate constants for the one-electron transfer between tetracyanoquino-dimethane and NNN′N′-tetramethyl-p-phenylenediamine were determined in acetonitrile solvent: k1=(4 ± 2)× 108 and k–1=(6 ± 2)× 109 l mol–1 s–1 at 23 ± 2°C.
A. Yamagishi, F. Watanabe and T. Masui, J. Chem. Soc., Chem. Commun., 1977, 273 DOI: 10.1039/C39770000273
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