As a result of the X-ray analysis on the thioenolether (4) the proposed structure of the tricyclic natural hydrocarbon albene has to be revised; further-more the relative configuration of the endo Diels–Alder adduct (3) is secured.
W. Kreiser, L. Janitschke and W. S. Sheldrick, J. Chem. Soc., Chem. Commun., 1977, 269 DOI: 10.1039/C39770000269
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