Issue 8, 1977
From the journal:

Journal of the Chemical Society, Chemical Communications

Stereochemistry and mechanism of cleavage of the platinum–carbon σ-bond by peroxy acid

Ian J. Harvie  and  Francis J. McQuillin  

Abstract

With m-chloroperbenzoic acid [(PhCHD)PtCl-(PPh3)2] yields [2H]benzyl m-chlorobenzoate and [2H]-benzyl alcohol with retention of stereochemistry at carbon, and the ratio of m-chlorobenzoate: alcohol product on oxidation of [(ArCH2)PtCl(PPh3)2](Ar = Ph or p-NO2C6H4) and of cis-[Bun2Pt(PPh3)2] depends on the polarity of the group which is cleaved; in [RhH(CO)(PPh3)3] the hydride is cleaved by ButO2H.

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Article information

DOI
https://doi.org/10.1039/C39770000241
Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 241-242

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Stereochemistry and mechanism of cleavage of the platinum–carbon σ-bond by peroxy acid

I. J. Harvie and F. J. McQuillin, J. Chem. Soc., Chem. Commun., 1977, 241 DOI: 10.1039/C39770000241

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