Hydrogen exchange has been observed between tritiated sodium borohydride and the aldehyde group of benzaldehyde, and is interpreted as due to a reverse hydride transfer (as a cage reaction) between borane and benzoxide ion, the primary products of the reduction.
C. Adams, V. Gold and D. M. E. Reuben, J. Chem. Soc., Chem. Commun., 1977, 182 DOI: 10.1039/C39770000182
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