Issue 6, 1977

Crystal structures of four complexes of quinquedentate macrocyclic ligands with novel co-ordination geometries containing five-co-ordinate silver(I), six-co-ordinate cadmium(II), six-co-ordinate mercury(II), and seven-co-ordinate cadmium(II)

Abstract

Metal complexes of two ‘N5’ macrocyclic ligands are five-co-ordinate (distorted pentagonal plane, M = AgI), six-co-ordinate (distorted pentagonal pyramid, M = CdII or HgII), or seven-co-ordinate (pentagonal bipyramid, M = CdII) depending upon the sizes of the metal ion and macrocycle.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 167-168

Crystal structures of four complexes of quinquedentate macrocyclic ligands with novel co-ordination geometries containing five-co-ordinate silver(I), six-co-ordinate cadmium(II), six-co-ordinate mercury(II), and seven-co-ordinate cadmium(II)

S. M. Nelson, S. G. McFall, M. G. B. Drew, A. H. B. Othman and N. B. Mason, J. Chem. Soc., Chem. Commun., 1977, 167 DOI: 10.1039/C39770000167

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