The rate of water exchange in the pentaco-ordinate CoII complex of 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane has been determined to be 4·2 × 104 s–1 at 25 °C with ΔH*= 36·5 ± 1·4 kJ mol–1 and ΔS*=–34 ± 4 J mol–1 K–1.
P. Meier, A. Merbach, S. Bürki and T. A. Kaden, J. Chem. Soc., Chem. Commun., 1977, 36 DOI: 10.1039/C39770000036
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