The enhancement in rate constant for the alkaline hydrolysis of diethyl 2-acetamidophenylphosphonate over that of the 4-isomer increases significantly with increasing dioxan content of the medium consistent with intramolecular assistance by the amido NH in the former reaction.
R. A. Naylor and A. Williams, J. Chem. Soc., Perkin Trans. 2, 1976, 1908 DOI: 10.1039/P29760001908
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