Issue 0, 1976

Tin oxide surfaces. Part 7.—An infrared study of the chemisorption and oxidation of organic Lewis base molecules on tin(IV) oxide

Abstract

Infrared spectroscopy has been used to show that hexachloroacetone is oxidised during chemisorption by tin(IV) oxide to produce a surface trichloroacetate, whereas the nitriles RC[triple bond, length as m-dash]N[R = CCl3, CH3, C(CH3)3] are converted to surface acetimidato anions, RCONH, on adsorption. The acetimidato anions may be converted to the corresponding carboxylates by heating in vacuo, or hydrolysed by water vapour at 320 K to the corresponding amides.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1976,72, 2484-2491

Tin oxide surfaces. Part 7.—An infrared study of the chemisorption and oxidation of organic Lewis base molecules on tin(IV) oxide

P. G. Harrison and E. W. Thornton, J. Chem. Soc., Faraday Trans. 1, 1976, 72, 2484 DOI: 10.1039/F19767202484

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