13  C nuclear magnetic resonance detection of thiol exchange on gold(I): significance in chemotherapy

Anvarhusein A. Isab; Peter J. Sadler

doi:10.1039/C3976001051B

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¹³C nuclear magnetic resonance detection of thiol exchange on gold(I): significance in chemotherapy

Anvarhusein A. Isab and Peter J. Sadler

Abstract

Thiols such as N-acetyl-L-cysteine react with aurothiomalate in aqueous solution at pH 7 to give Au₄(SR)₇^3– clusters which undergo fast exchange with RS^– but not RSH.

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DOI: https://doi.org/10.1039/C3976001051B
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1976, 1051b-1052

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¹³ C nuclear magnetic resonance detection of thiol exchange on gold(I): significance in chemotherapy

A. A. Isab and P. J. Sadler, J. Chem. Soc., Chem. Commun., 1976, 1051b DOI: 10.1039/C3976001051B

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Journal of the Chemical Society, Chemical Communications