Fluorination of diazo-ketones with CF3OF produces a mixture of αα-difluoro-ketones and α-trifluoro-methoxy-α-fluoro-ketones by the initial electrophilic attack on the diazo-group followed by nucleophilic attack with F– or CF3O–.
C. Wakselman and J. Leroy, J. Chem. Soc., Chem. Commun., 1976, 611a DOI: 10.1039/C3976000611A
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