Issue 24, 1976

2,9,10-Trioxa-6-aza-1-silatricyclo[4,3,3,01,6]dodecane. A novel heterocyclic system: synthesis, X-ray crystal and molecular structure of the 1-chloromethyl derivative

Abstract

A representative of the novel heterocyclic system, 1-chloromethyl-2,9,10-trioxa-6-aza-silatricyclo-[4,3,3,01,6]dodecane, has been synthesized and the geometry and molecualr packing in the crystal have been determined by X-ray analysis; the presence of apparently shortened interatomic distances in a rather rigid 6-membered heterocycle has been established, as well as the disorder of the 5-membered heterocycles.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 1041-1042

2,9,10-Trioxa-6-aza-1-silatricyclo[4,3,3,01,6]dodecane. A novel heterocyclic system: synthesis, X-ray crystal and molecular structure of the 1-chloromethyl derivative

A. Kemme, J. Bleidelis, I. S. G. Zelchan and E. Lukevics, J. Chem. Soc., Chem. Commun., 1976, 1041 DOI: 10.1039/C39760001041

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